
When distilling alcohol, it is important to separate the heads, body, and tails by taste and smell. The heads, which contain compounds such as methanol and acetone, have a pungent smell and taste, resembling nail polish remover. While it is advised to discard the heads, some people choose to keep them for use as fire starters for BBQs. In the context of moonshine, the heads may contribute to the characteristic smell of nail polish remover, which is caused by the presence of acetone or ethyl acetate.
| Characteristics | Values |
|---|---|
| Cause of the smell | Acetic acid bacteria |
| Product of the bacteria | Ethyl Acetate |
| Other possible causes | Fusel alcohols, acetaldehyde, large amounts of simple sugars, high temperature |
| Solution | Dilute with water, use yeast/recipes that are better for high-temperature fermentation |
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What You'll Learn

The heads of distillate can smell like nail polish remover
The heads of distillate can sometimes smell like nail polish remover. This is due to the presence of ethyl acetate, a common ester that gives off a chemical-like aroma and taste. While small amounts of ethyl acetate can add complexity to certain spirits, higher concentrations can result in an unpleasant, off-putting flavour.
The heads of the distillate are the first portion of the run and are often discarded due to their unpleasant smell and high alcohol content. The heads can also contain other undesirable compounds such as methanol, acetaldehyde, and fusel oils, which can contribute to harsh flavours and aromas. Methanol, in particular, is toxic and can cause severe health problems if ingested in large quantities.
To remove the nail polish remover smell and improve the quality of the distillate, distillers may employ various techniques. One method is to distil again, ensuring that the foreshots, or the first portion of the distillate, are discarded. Using filters, such as the EZ Filter or Filter Pro, can also help polish the spirit and remove any residual aromas.
Additionally, controlling the fermentation temperature can be crucial in preventing the formation of ethyl acetate. Keeping the temperature below 70°F (21°C) or using yeast and recipes suitable for high-temperature fermentation can help reduce the likelihood of ethyl acetate development.
Distillers may also utilise specific types of yeast and adjust fermentation processes to minimise the production of harsh-tasting and smelling compounds. By taking these steps, distillers can aim to produce a smoother and more refined final product.
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This is due to acetone, a product of acetic acid bacteria
Moonshine, a distilled alcoholic drink, can sometimes smell like nail polish remover. This is due to acetone, a product of acetic acid bacteria. Acetone is a compound that is produced when the reaction to make vinegar is not completed. The process by which this happens involves acetic acid bacteria turning alcohol into vinegar. The chemical pathway is as follows: Alcohol (Ethanol) + Oxygen -> Acetaldehyde + Oxygen -> Acetic Acid + Water.
Acetaldehyde, an intermediate step in the process, has a strong smell similar to acetone and nail polish remover. This can occur when there is a higher residual alcohol content in the mixture, and bacteria attempt to metabolize this alcohol to acetic acid but are limited by a lack of oxygen. This can happen when a lid is placed on the mixture, preventing oxygen from entering.
Additionally, during the distillation process, the heads or foreshots of the distillate, which have an unpleasant smell like nail polish remover, are usually discarded. This is done to improve the taste and remove unwanted compounds. The heads comprise approximately 2% of the first distillation and have a very high alcohol percentage, typically 80% or higher.
It is important to note that while the smell of acetone or nail polish remover may be undesirable, it does not indicate any health or safety issues. However, it may take considerable aging or additional processing to reduce the presence of acetone and improve the smell and taste of the product.
To avoid the nail polish remover smell in future batches, it is recommended to control the fermentation temperature to keep it below 70 degrees Fahrenheit or use yeast and recipes that are better suited for high-temperature fermentation.
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High temperatures can cause this smell
Moonshine, or distilled alcohol, can sometimes smell like nail polish remover. This is due to the presence of acetone, or ethyl acetate, which is produced by acetic acid bacteria acting on alcohol. While this may be indicative of a problem with the distillation process, it is not necessarily harmful.
High temperatures can cause the nail polish remover smell in moonshine. When distilling alcohol, the temperature must be carefully controlled. Alcohol boils at around 78°C, while water does not evaporate until it reaches 100°C. By gently heating a mixture of water and alcohol, the alcohol will evaporate first and can be separated through distillation. However, if the temperature is too high, it can cause the production of fusel alcohols, which are higher-weight alcohols that can give off an unpleasant odour.
To avoid the nail polish remover smell, it is recommended to keep the fermentation temperature below 70°F (21°C). This can be achieved by using yeast and recipes that are better suited for high-temperature fermentation, such as K1V or D21. Controlling the temperature will help prevent the formation of fusel alcohols and the associated unpleasant smell.
Additionally, high temperatures can also affect the flavour and taste of the final product. The heads of the distillate, which contain compounds like methanol and acetone, have an unpleasant smell and taste. By separating and removing the heads during the distillation process, you can improve the quality of the moonshine.
It is important to note that distillation requires careful monitoring and adjustments to ensure the desired outcome. Distillers should be cautious and well-informed about the process to avoid any potential health risks associated with improper distillation.
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Raw vinegar may have a higher ABV, causing the smell
Moonshine is an alcoholic drink made through distillation. The distillation process involves separating water and alcohol by heating them. Since alcohol has a lower boiling point than water, it evaporates first and can be separated by condensing the vapour.
During the distillation process, it is important to separate the heads, hearts, and tails of the distillate. The heads, which constitute the first portion of the run, have an unpleasant odour resembling nail polish remover or acetone. While the hearts are the desired pure alcohol, the tails can also be unpleasant, smelling like methylated spirits. The heads and tails are typically discarded or used for other purposes, such as fire-starting.
The smell of nail polish remover, or acetone, is characteristic of the heads of the distillate and is typically considered undesirable. This smell is caused by the presence of acetaldehyde, which can be the result of several factors, including infection, insufficient oxygen, underpitching, or incorrect fermentation temperature.
Raw vinegar is produced by fermenting alcoholic drinks with acetic acid bacteria, which convert ethanol into acetic acid. The ABV of the vinegar will depend on the starting material and the fermentation process. While most vinegars have an ABV between 6-15%, some can have higher ABVs. For example, a 6.5% ABV cider can produce vinegar with an ABV of up to 6.5%. Additionally, store-bought raw vinegars can be less consistent due to the manufacturing process, which may result in higher ABV levels.
While higher ABV levels in raw vinegar are possible, it is important to note that vinegar production is typically aimed at achieving a target vinegar acidity, which is influenced by the starting ABV. Therefore, while a higher ABV may contribute to a stronger vinegar smell, it is not the sole factor, and the presence of other compounds and impurities can also affect the overall aroma.
In conclusion, while raw vinegar may have a higher ABV, it is not the only factor contributing to its smell. The unique odour of nail polish remover in moonshine is specifically attributed to the heads of the distillate and the presence of acetaldehyde. The distillation process aims to separate and discard these undesirable components, resulting in a purer alcoholic product.
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The smell can be caused by stalled fermentation
Moonshine, or any other alcoholic drink, can sometimes smell like nail polish remover. This is because of the presence of ethyl acetate, which is a product of acetic acid bacteria. This can occur when fermentation has stalled, allowing the bacteria to take hold. Acetic acid bacteria require a lot of oxygen to grow, so they usually won't grow in active fermentation.
If you are making your own moonshine, it is important to separate the heads, hearts, and tails. The heads, which are the first portion of the run, will smell like nail polish remover and should be discarded. This is approximately 2% of the first distillation. If you are unsure, you can compare a sample of the hearts to a sample of the heads to determine if it needs to be cut.
The smell of nail polish remover can also be caused by large amounts of simple sugars, such as honey, being used in the fermentation process. Additionally, high temperatures can also contribute to this smell. In the case of mead, aging the beverage for a long time can help to mellow out the smell and taste.
It is important to note that consuming beverages with an ethyl acetate smell should be avoided as it can indicate the presence of harmful bacteria.
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Frequently asked questions
No, it shouldn't. The presence of ethyl acetate, which smells like nail polish remover, is usually due to acetic acid bacteria.
The nail polish remover smell is due to the presence of ethyl acetate, which is a product of acetic acid bacteria.
You can prevent the nail polish remover smell by controlling the fermentation temperature and using yeast/recipes that are better for high-temperature fermentation.
Large amounts of simple sugars, such as honey, and high temperatures can also cause unusual smells in moonshine.
The heads of the distillate have an unpleasant smell like nail polish remover. You can identify and separate them by their smell, and throw them away or use them as fire starters for your BBQ.










































